Reduction products of dinuclear [Rh2Cl2(CO)2 {μ-(PhO)2PN(Et)P(OPh)2}2]. Crystal structure of [Rh2HgCl(μ-H)(CO)2 {μ-(PhO)2PN(Et)P(OPh)2}2] |
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| Authors: | John S Field Raymond J Haines Elsie Meintjies Beate Sigwarth Petrus H Van Rooyen |
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| Institution: | C.S.I.R. Unit of Metal Cluster Chemistry, Department of Chemistry, University of Natal, P.O. Box 375, Pietermaritzburg, 3200 Republic of South Africa;National Chemical Research Laboratory, C.S.I.R., P.O. Box 395, Pretoria, 0001 Republic of South Africa |
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| Abstract: | Treatment of Rh2Cl2(CO)2 {μ-(PhO)2PN(Et)P(OPh)2}2] with various reducing agents gives a number of products, the type depending on the conditions employed. The products isolated include Rh2(CO)2{μ-(PhO)2PN(Et)P(OPh)2}2], Rh2(CO)3{μ-(PhO)2PN(Et)P(OPh)2}2],and Rh2HgCl(μ-H)(CO)2{μ-(PhO)2PN(Et)P(OPh)2}2]; the structure of the last complex was determined by X-ray diffraction. |
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