Complexes carbeniques des ferroporphyrines: Preparation de complexes carbeniques comportant deux substituants electrodonneurs par alcoolyse ou thionolyse des complexes halogenocarbeniques correspondants |
| |
| Authors: | Jean-Paul Battioni Daniel Dupre Philippe Guerin Daniel Mansuy |
| |
| Institution: | Laboratoire de Chimie de l''Ecole Normale Supérieure, associé au C.N.R.S., L.A. 32, 24 rue Lhomond, 75231 Paris Cedex 05 France |
| |
| Abstract: | α-Halocarbeneporphyriniron complexes, Fe(P)(C(Cl)R) react with alcohols or thiols with substitution of the chlorine atom by OR′ or SR′ groups. This reaction has been used to obtain new carbeneporphyriniron complexes in which the carbene ligand is substituted by two electrodonating groups. The complexes Fe(P)(C(XR′)R) with XR′ = OCH3 or OC2H5, R = CH3 or (CH3)2CH and P = TPP (tetraphenylporphyrin) or TTP (tetratolylporphyrin) and with XR′ = SCH2C6H5, R = CH3 and P = TPP or TTP, have been isolated and fully characterized. |
| |
| Keywords: | Author to whom correspondence should be addressed |
| 本文献已被 ScienceDirect 等数据库收录！ |
