Reversal of the bonding mode of μ-C7H7 on an FeRh framework: Synthesis and structure of (μ-C7H7)(μ-CO)Fe(CO)2Rh(dppe)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

Reversal of the bonding mode of μ-C7H7 on an FeRh framework: Synthesis and structure of (μ-C7H7)(μ-CO)Fe(CO)2Rh(dppe)

Authors:	Gong-Yu Lin Josef Takats

Institution:	Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2G2 Canada

Abstract:	Phosphine ligands rapidly displace one or two carbonyl groups from (μ-C₇H₇)F $e(CO)_{3} R$ h(CO)₂ (I). The substitution occurs exclusively at the Rh center and proceeds with reversal of the bonding mode of the μ-C₇H₇ moiety from η⁴-Rh and η³-Fe in I to η³-Rh and η⁴-Fe in μ-C₇H₇)(μ-CO)Fe(CO)₂Rh(dppe).

Keywords:
本文献已被 ScienceDirect 等数据库收录！