Reactivity of bis(diphenylphosphinomethyl)phenylphosphine-bridged trinuclear rhodium complexes: Cluster families related by reversible carbon monoxide binding and oxidative addition |
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| Authors: | Alan L. Balch Rosalvina R. Guimerans Marilyn M. Olmstead |
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| Affiliation: | Department of Chemistry, University of California, Davis, California 95616 U.S.A. |
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| Abstract: | The preparation and interconversion of the following clusters bridged by bis(diphenylphosphinomethyl)phenylphosphine (dpmp) are reported: [Rh3(μ-dpmp)2(CO)aXb][BPh4]; X = I, a = 2, 3, 4, b = 2; X = I, a = 3, 2, 1, b = 4; X = I, a = 1, b = 6. The structure of one of these, [Rh3(μ-dpmp)2(CO)I4][BPh4], has been determined by X-ray diffraction. |
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