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Synthesis and properties of a thermally stable methyltitanium(IV) compound: Cyclopentadienylmethyldichlorotitanium(IV)
Authors:Gordon J. Erskine  Graham J.B. Hurst  Erica L. Weinberg  Brian K. Hunter  James D. McCowan
Affiliation:Department of Chemistry, Queen''s University, Kingston, Ontario, K7L 3N6 Canada
Abstract:η5C5H5Ti(CH3)Cl2 and η5-C5H5Ti(C2H5TiCl2 have been synthesized. The reactivity of the methyl compound is much greater than that of the closely related sandwich compound, (η5-C5H5)2Ti(CH3)Cl, but the thermal stability is comparable.
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