Synthesis and properties of a thermally stable methyltitanium(IV) compound: Cyclopentadienylmethyldichlorotitanium(IV) |
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Authors: | Gordon J. Erskine Graham J.B. Hurst Erica L. Weinberg Brian K. Hunter James D. McCowan |
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Affiliation: | Department of Chemistry, Queen''s University, Kingston, Ontario, K7L 3N6 Canada |
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Abstract: | η5C5H5Ti(CH3)Cl2 and η5-C5H5Ti(C2H5TiCl2 have been synthesized. The reactivity of the methyl compound is much greater than that of the closely related sandwich compound, (η5-C5H5)2Ti(CH3)Cl, but the thermal stability is comparable. |
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