Chemicals from Synthesis Gas : By Robert A. Sheldon (Series: Catalysis by Metal Complexes) D. Reidel Publishing Company,Dordrecht, The Netherlands, 1983, xx + 216 pages,Dfl. 110.00, US$ 48.00. ISBN 90-277-1489-4. |
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| Authors: | GJ Leigh |
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| Institution: | AFRC Unit of Nitrogen Fixation, University of Sussex, Brighton BN1 9RQ Great Britain |
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| Abstract: | Photolysis of cis-HMn(CO)4PPh3 in the presence of H2 and 1-alkene results in catalytic hydrogenation and isomerization of the alkene. The isomerization leads to cis- and trans-2-alkene in the presence or absence of H2. Catalytic hydrogenation also occurs when cis-CH3Mn(CO)4PPh3 is irradiated in the presence of H2; use of D2 leads exclusively to CH3D. The possible mechanism of the hydrogenation is discussed. |
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