Insertion of the Pt(PPh3)2 unit into inorganic triatomic rings coordinated to metal—ligand moieties |
| |
| Authors: | Massimo Di Vaira Simonetta Moneti Maurizio Peruzzini Piero Stoppioni |
| |
| Institution: | Dipartimento Di Chimica, Università, Istituto I.S.S.E.C.C., C.N.R., Via J. Nardi, 39, 5013 2 Firenze Italy |
| |
| Abstract: | Reaction of the (triphos)Co(E2S)]BF4 complexes (triphos = 1,1,1-tris(di-phenylphosphinomethyl)ethane, E = P or As) containing the P2S or As2S cyclic units trihapto(η3-bonded to the metal, with (C2H4)Pt(PPh3)2 involves insertion of the Pt(PPh3)2 moiety into a bond of the inorganic ring, yielding the compounds (triphos)Co(E2S)Pt(PPh3)2]BPh4 (E = P or As), whose structures have been determined by X-ray diffraction studies. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
