The interaction of dihydrofurylsilanes with dichlorocarbene under phase-transfer conditions |
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Authors: | E Lukevics VN Gevorgyan YS Goldberg AP Gaukhman MP Gavars JJ Popelis MV Shymanska |
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Institution: | Institute of Organic Synthesis, Latvian SSR Academy of Sciences, 21 Aizkraukles St., Riga U.S.S.R. |
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Abstract: | Dichlorocarbene generated in a two-phase catalytic system reacts with 3-trimethylsilyl-2,5-dihydrofuran to give both possible products of mono-insertion into the CH bond in positions 2 and 5 of the ring, together with a CC bond adduct. Reaction of 2-trimethylsilyl-4,5-dihydrofuran with dichlorocarbene leads to 2,3-dichloro-2-trimethylsilyl-5,6-dihydro-2H-pyran, which is formed via isomerization of the primary bicyclic adduct. |
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Keywords: | Address for correspondence |
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