Electrochemical studies of group III alkyl derivatives: II. Synthesis of adducts of trimethylindium and trimethylgallium |
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Authors: | Anthony C. Jones Neil D. Gerrard David J. Cole-Hamilton A.Kenneth Holliday J.B. Mullin |
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Affiliation: | Donnan Laboratories, University of Liverpool, P.O. Box 147, Liverpool, L69 3BX Great Britain;Royal Signals Research Establishment, St. Andrews Road, Great Malvern, Worcs. W14 3PS Great Britain |
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Abstract: | Electrolysis of methylmagnesium chloride or dimethylmagnesium in tetrahydrofuran (thf) with an indium anode yields the spectroscopically characterised adduct Me3In · thf directly; the adducts Me3In · L (L = NEt3, PMe3, PEt3) are obtained by direct addition of excess L to Me3In · thf. |
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