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光致变色化合物环化量子产率的测定
引用本文:牛丽红,赵福群,周云,杨锦,尉京志. 光致变色化合物环化量子产率的测定[J]. 大学化学, 2015, 30(4): 30-35. DOI: 10.3866/pku.DXHX20150430
作者姓名:牛丽红  赵福群  周云  杨锦  尉京志
作者单位:清华大学化学系 北京100084
摘    要:量子产率是光化学反应中一个重要的物理量。实验中选用二芳基乙烯类光致变色化合物,利用自行搭建的装置,开发了一个测定光化学反应量子产率的新实验,用于中级化学实验教学中。实践表明,该实验加深了学生对相关理论原理和应用的理解,提高了学生自主实验能力和实验兴趣。

关 键 词:量子产率  光化学反应  光致变色  

Measuring the Cyclization Quantum Yield of Photochromic Diarylethene
Niu Lihong,Zhao Fuqun,Zhou Yun,Yang Jin,Wei Jingzhi. Measuring the Cyclization Quantum Yield of Photochromic Diarylethene[J]. University Chemistry, 2015, 30(4): 30-35. DOI: 10.3866/pku.DXHX20150430
Authors:Niu Lihong  Zhao Fuqun  Zhou Yun  Yang Jin  Wei Jingzhi
Affiliation:Department of Chemistry, Tsinghua University, Beijing 100084, China
Abstract:Quantum yield is an important parameter in photochemistry. Diarylethene, as a kind of photochromic compound, is used in the experiment. We have validated the method for measuring the quantum yield in the photochemical reaction using the in-house made setup and applied this experiment to the comprehensive laboratory course. This experiment facilitates a better understanding of the principles and the applications, and the students' ability and interest to conduct an experiment are improved.
Keywords:Quantum yield  Photochemistry reaction  Photochromic
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