Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II) |
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| Authors: | Saira Shahzadi Saqib Ali Amin Badshah Farkhanda Shaheen Fiaz Ahmed Mohammed Fettouhi |
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| Institution: | (1) Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320, Pakistan;(2) NESCOM, P. O. Box 2216, Islamabad, Pakistan;(3) Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia |
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| Abstract: | The complex bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8) ?, b=18.7305(16) ?, c=11.9933(10) ?, β=107.074(1)°, V=1857.3(3) ?3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties. |
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| Keywords: | Dithiocarbamate Palladium(II) complex Crystal structure |
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