首页 | 本学科首页   官方微博 | 高级检索  
     


The polarised frozen-core approximation: Oscillator strengths for the boron isoelectronic sequence
Authors:R.P. McEachran  M. Cohen
Affiliation:Department of Physical Chemistry, The Hebrew University, Jerusalem, Israel
Abstract:Orbital wave functions of a large number of ns-, np-, and nd-levels of the first five members of the boron isoelectronic sequence have been calculated using a frozen-core Hartree-Fock procedure augmented by an l-dependent core polarisation potential. The calculated ionisation energies are generally in very good agreement with observations. Electric dipole oscillator strenghts have been derived from the calculated orbitals and energies and have been used to yield simple interpolation formulae for f-values of higher members of the sequence. They are expected to be of high accuracy in many cases.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号