Proton transfer reactions from N-H acid [5,10,15,20-tetrakis(pentafluorophenyl)-21-H, 23-H-porphyrin] to strong bases in acetonitrile期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Proton transfer reactions from N-H acid [5,10,15,20-tetrakis(pentafluorophenyl)-21-H, 23-H-porphyrin] to strong bases in acetonitrile

Authors:	Grzegorz Schroeder Bogumi Brzezinski Dariusz Podbski Eugeniusz Grech

Affiliation:	Grzegorz Schroeder, Bogumi Brzezinski, Dariusz Podbski,Eugeniusz Grech

Abstract:	Deprotonation of 5,10,15,20-tetrakis(pentafluorophenyl)-21-H, 23-H-porphyrin (PhF₅PorH₂) by various bases has been studied by ¹H NMR and kinetic methods. The kinetic parameters in acetonitrile were defined for proton transfer reactions yielding [NH]⁺ protonated bases and [NHN]⁻ anions with intramolecular hydrogen-bonded chains.

Keywords:	Proton transfer Hydrogen-bonded chains Porphyrin Phosphazenes MTBD TBD
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