Molecular and crystal structure of bis{1,4-bis(1,2,4-triazol-1-yl)butane}dibromocadmium(II) |
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Authors: | L. Shen |
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Affiliation: | 1.Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, College of Material Chemistry and Chemical Engineering,Hangzhou Normal University,Hangzhou,P.R. China |
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Abstract: | The structure of [Cd(Btb)2Br2] (I) (Btb = 1,4-bis(triazol-1-yl)butane) exhibits a two-dimensional (4,4) network through Btb-bridge in which the Cd(II) atom is in a distorted octahedral environment formed by four nitrogen atoms of the triazoles and two trans-Br atoms. The crystals are monoclinic, space group P21/n with a = 7.6778(6), b = 18.2237(8), c = 8.7655(5) Å, β = 113.4534(19)°. The Btb ligand demonstrates the completely anti conformation. |
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