| 定标粒子理论研究HPLC分子间相互作用对K'的影响 |
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| 引用本文： | 张维冰,史景江.定标粒子理论研究HPLC分子间相互作用对K'的影响[J].化学学报,1993,51(10):943-949. |
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| 作者姓名： | 张维冰 史景江 |
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| 作者单位： | 齐齐哈尔轻工业学院化工系 |
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| 摘 要： | 本文以统计热力学的观点, 对流动相和固定相分别采用定标粒子理论和点阵模型研究HPLC过程中溶质分子与流动相分子、固定相分子之间的相互作用, 得到了描述分子间相互作用与K'之间定量关系的关联方程, 并通过实验对该方程加以验证。
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| 关 键 词： | 液体色谱 定标粒子理论 统计热力学 分子间相互作用 |
Study on the effect of the intermolecular force to the capacity ratio in HPLC by sealed particle theory |
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| Abstract: | To study the effect of the intermol. force to the capacity ratio in HPLC, the scaled particle theory and the two dimension lattice theory were resp. applied to study intermol. interaction between the solvent mols. and the solute mols. in the liquid phase and on the stationary phase. The authors also derived a quant. relationship between retention value and the intermol. force, and the equation was testified by experimentc |
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| Keywords: | LIQUID CHROMATOGRAPHY SCALED PARTICLE THEORY STATISTICAL THERMODYNAMICS INTERMOLECULAR INTERACTION |
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