Vibrational assignments for trimethylene oxide and several deuterated analogues |
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| Affiliation: | 1. Department of Chemistry and Biochemistry & Center for Nanoscience, University of Missouri – St. Louis, Saint Louis, MO 63121, USA;2. Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, IL 62026, USA;1. I. Physikalisches Institut, Universität zu Köln, Zülpicher Str. 77, 50937 Köln, Germany;2. Department Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany;3. Institut für Physikalische Chemie, Karlsruher Institut für Technologie (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany;4. Institut für Physikalische Chemie und Elektrochemie, Lehrgebiet A, Leibniz Universität Hannover, Callinstr. 3-3A, 30167 Hannover, Germany;1. Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, D-52074 Aachen, Germany;2. Laboratoire Modélisation et Simulation Multi Echelle, MSME UMR 8208 CNRS, Université Paris-Est, 5 bd. Descartes, F-77454 Marne-la-Vallée, France;3. Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), CNRS UMR 7583, Université Paris-Est Créteil, Université Paris Diderot, 61 avenue du Général de Gaulle, F-94010 Créteil cedex, France;1. Chemistry-School of Natural and Environmental Sciences, Newcastle University, Bedson Building, Newcastle-upon-Tyne NE1 7RU, UK;2. School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, UK;1. Chemical Department, Samara State Technical University, Molodogvardeyskaya str, 224, 443100, Samara, Russian Federation;2. Department of Physical Chemistry, Kazan Federal University, Kremlevskaya str. 18, 420008, Kazan, Russian Federation;3. Department of Physics, Mathematics and Medical Informatics, Tver State Medical University, Sovetskaya 4, 170100, Tver, Russian Federation;4. Department of General Physics, Physics and Technical Faculty, Tver State University, Zhelyabova 33, 170100, Tver, Russian Federation;5. EAHS DCSD 1701 Mountain Industrial Blvd, Stone Mountain, GA 30083, USA;1. Centro de Investigação em Química, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, P-4169-007 Porto, Portugal;2. Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, MD 21250, USA |
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| Abstract: | Complete vibrational assignments below about 1400 cm−1 are presented for trimethylene oxide and its deuterated derivatives β-d2, α, α′-d4, d6, and α-d2, on the basis of the i.r. vapour phase spectra and the spectra of the solids at 15 K as thin films and in argon matrices, and the Raman spectra of the vapours and liquids. Previously reported assignments for the CH stretching, CH2 scissoring, and the ring puckering vibrations, as well as preliminary assignments for the CD stretching modes, are included for comparison. |
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