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A simple synthesis of acetyl and propionyl cyclododecanes |
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| Authors: | L I Zakharkin V V Guseva G N Antonova |
| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| Abstract: | 1-Formyl-4,8-cyclododecadiene, obtained by hydroformylation of 1,5,9-cyclododecatriene, reacts with MeMgHal or EtMgHal to give 1-(l -hydroxyethyl)-or 1-(l-hydroxypropyl)-4,8-cyclododecadiene, respectively. The hydrogenation of their double bonds and subsequent oxidation of the resulting alcohols afford, in high yields, acetyl- or propionylcyclododecane, respectively.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 418–419, February, 1993. |
| Keywords: | 1Z 5E 9E-cyclododecatriene l-formyl-4Z 8E-cyclododecadiene 1-(l |
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