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A new, simple, and mild azidolysis of vinylepoxides |
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| Authors: | Giuliana Righi Livia Salvati ManniPaolo Bovicelli Romina Pelagalli |
| Institution: | a Istituto di Chimica Biomolecolare, Dip. Chimica, Università Sapienza di Roma, p.le Aldo Moro 5, 00185 Roma, Italy b Istituto di Chimica Biomolecolare, Traversa La Crucca 3, Baldinca, I-07040 Sassari, Italy c Dip.Chimica, Università Sapienza di Roma, p.le Aldo Moro 5, 00185 Roma, Italy |
| Abstract: | A new, simple, and mild regio-and stereocontrolled azidolysis of vinylepoxides with TMSN3/BF3 system is reported. The method appears of general value and works very well particularly in the presence of electron-poor olefins, regardless of the size of substituents on the heterocyclic ring. |
| Keywords: | Vinylepoxides Azidolysis Regioselectivity Azido alcohols |
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