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The thermodynamic properties of solutions of sodium chloride,water, and 1-propanol
Authors:M N Mamontov  N M Konstantinova  E S Veryaeva  I A Uspenskaya
Institution:1.Faculty of Chemistry,Moscow State University,Moscow,Russia
Abstract:The temperature-concentration dependences of the activity coefficient of NaCl in aqueous solutions of 1-propanol at 298 and 318 K, solution ionic strength up to 3m, and alcohol contents of 10–40 wt % were determined by the method of electromotive forces with ion-selective electrodes. The results were used to estimate interaction parameters in the Pitzer model. The Darken method was used to calculate the integral Gibbs energy of solutions.
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