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A mode-mode coupling theory of chemical reaction in a dense fluid |
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| Authors: | Myung S Jhon John S Dahler |
| Institution: | (1) Departments of Chemistry and Chemical Engineering, University of Minnesota, Minneapolis, Minnesota |
| Abstract: | A study is made of the coupling between chemical reaction and diffusion in a dense fluid. Our analysis utilizes the projection operator formalism and a generalized Langevin equation that is based on irreversible, phenomenological equations of motion instead of conventional Hamiltonian mechanics. It also is shown that this same  non-Hamiltonian theory provides a simple way of deriving Kawasaki's mode-mode coupling theory of diffusion.This research was supported by a grant from the National Science Foundation. |
| Keywords: | Projection operator mode-mode coupling non-Hamiltonian method chemical reaction bimolecular reaction hydrodynamicmode reactive mode diffusion-controlled reaction |
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