Influence of substitution at the benzylic position on the behavior of stereoisomeric phosphorus compounds as precursors of stabilized carbon-centered radicals |
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| Authors: | Pérez-Prieto Julia Galian Raquel Eugenia Burgos Pascual Oña Morant Miñana Maria del Carmen Miranda Miguel Angel López-Ortiz Fernando |
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| Institution: | Departamento de Química Orgánica/ICMOL, Universidad de Valencia, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain. julia.perez@uv.es |
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| Abstract: | Efficient benzylic radical formation from benzod]-1,2-oxaphospholes has demonstrated their suitability as precursors of stabilized C-centered radicals, a property associated with antioxidant potential. A remarkable stereodifferentiation is observed for alkyl- and aryl-substituted derivatives. reaction: see text] |
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