In situ transmission electron microscopy observation of the growth of bismuth oxide whiskers. |
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Authors: | T Mima Y Takeuchi S Arai K Kishita K Kuroda H Saka |
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Affiliation: | Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan. |
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Abstract: | Growth of bismuth oxide (most probably Bi2O3) was observed in situ in a transmission electron microscope. Bi liquid particles were dispersed on the substrates of diamond or SiO2. Introduction of oxygen up to 5 x 10-4 Pa resulted in formation of bismuth oxide (most probably Bi2O3) whiskers. The growth mechanism of the whisker was discussed in terms of a vapor-liquid-solid (VLS) mechanism. It is suggested that the liquid droplet of Bi acts as a physical catalyst for growth of bismuth oxide (most probably Bi2O3) whiskers. |
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