Direct incorporation of A 6α(7α)-formamido group into penicillins and cephalosporins |
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Authors: | Michael J Pearson |
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Institution: | Beecham Pharmaceuticals, Research Division, Brockham Park, Betchworth, Surrey, RH3 7AJ Great Britain |
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Abstract: | 6β(7β)-(-2,2,2-Trichloroethoxycarbonyl--trifluoromethanesulphonylamino) penicillins and cephalosporins have been converted into the corresponding 6α(7α)-formamido-6β(7β)-2,2,2-trichloroethoxycarbonylamino derivatives, by treatment with ,-bis(trimethylsilyl) formamide and triethylamine. |
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