Synthesis of (S-(−)-wybutine,the fluorescent minor base from yeast phenylalanine transfer ribonucleic acids |
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| Authors: | Taisuke Itaya Akemi Mizutani |
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| Affiliation: | Faculty of Pharmaceutical Sciences, Kanazawa University, Takara-machi, Kanazawa 920, Japan |
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| Abstract: | The Wittig reaction of 1-benzyl-7-formylwye (12) with (R)-[2-carboxy-2-[(methoxycarbonyl)amino]ethyl]triphenylphosphonium chloride (8) followed by successive methylation and reduction gave (-)-wybutine [(S)-1a]. |
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