Reaction of t-butoxy radicals with norbornadiene |
| |
| Authors: | W.Ken Busfield Ian D. Jenkins San H. Thang Ezio Rizzardo David H. Solomon |
| |
| Affiliation: | School of Science, Griffith University, Nathan, QLD. 4111. Australia;C.S.I.R.O., Division of Applied Organic Chemistry, G.P.O. Box 4331, Melbourne, VIC. 3001. Australia. |
| |
| Abstract: | 95 percent of the reaction of t-butoxy radical with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearrangement involving a 1,3-H shift and some radical abstraction observed for the first time. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
