2,6-Dimethylphenylnitrene in low-temperature matrices |
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| Authors: | Ian R Dunkin Thomas Donnelly Thomas S Lockhart |
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| Institution: | Department of Pure and Applied Chemistry, University of Strathclyde , 295 Cathedral Street, Glasgow. G1 1XL UK |
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| Abstract: | Photolysis of 2,6-dimethylphenyl azide in N2 matrices at 12K gives 2,6-dimethylphenylnitrene; in the presence of CO, the nitrene forms the corresponding isocyanate, while on shorter wavelength irradiation, it undergoes an inefficient rearrangement to an azacycloheptatetraene. |
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