Phenyl selenium trichloride in synthesis. Reaction with ketones. A new variation of the selenoxide elimination reaction |
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| Authors: | Lars Engman |
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| Affiliation: | Department of Organic Chemistry, Royal Institute of Technology S-100 44 Stockholm, Sweden |
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| Abstract: | Phenyl selenium trichloride was used for the introduction of a PhSeCl2-group into the α-position of ketones. These products were converted to enones (hydrolysis/selenoxide elimination) or α-phenylselenoketones (thiourea-reduction). |
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