Short intramolecular Diels-Alder approach to functionalized spiro[4.5]decanes |
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Authors: | Jan-E Nyström Terrence D McCanna Paul Helquist Ramnath S Iyer |
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Institution: | Departments of Chemistry, University of Notre Dame, Notre Dame, Indiana 46556 U.S.A.;State University of New York, Stony Brook, New York 11794 U.S.A. |
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Abstract: | The intramolecular Diels-Alder reaction of a (5′-hexynyl)cyclopentadiene provides a 1,2-tetramethylene-bridged norbornadiene which undergoes selective monohydrogenation followed by ozonolysis to provide the title compounds. |
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