Asymmetric induction in the cycloaddition reaction of dichloroketene with chiral enol ethers. A versatile approach to optically active cyclopentenone derivatives. |
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Authors: | Andrew E. Greene Florence Charbonnier |
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Affiliation: | Université Scientifique et Médicale de Grenoble (LEDSS) Bat. 52 - Chimie Recherche - BP 68 38402 SAINT MARTIN D''HERES CEDEX - France |
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Abstract: | Significant asymmetric induction has been observed in the cycloaddition reaction of dichloroketene with chiral enol ethers. The resultant diastereomeric cyclobutanones have been converted to synthetically useful α-chlorocyclopentenones in optically active form. |
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