Synthesis of the spirocyclic center of fredericamycin a by phenoxy-enoxy radical coupling期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Synthesis of the spirocyclic center of fredericamycin a by phenoxy-enoxy radical coupling

Authors:	Andrew S Kende Frank H Ebetino Toshiharu Ohta

Institution:	Department of Chemistry, University of Rochester Rochester, NY 14627 USA

Abstract:	Ferricyanide oxidation of the dianions of phenolic β-diketones $2$ effects intramolecular phenoxy-enoxy radical coupling to form spiro systems derived from C-C bond formation $para$ or $ortho$ to the phenolic oxygen.

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