Sterisch gehinderte Alkene,VII Röntgenstrukturanalyse und Reaktionen des Tetrakis-(2-formyl-2-propyl)ethens |
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| Authors: | Adolf Krebs Wolf-Ulrich Nickel Liane Tikwe Jürgen Kopf |
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| Affiliation: | Institut für Organische Chemie und Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, D - 2000 Hamburg 13 Germany |
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| Abstract: | The tetraaldehyde {=1} was synthesized by ozonation of the triene {=3}. The C=C-bond in {=1} is twisted by 28.6° and the CC-bond and the allylic bond lengths are significantly elongated to 135.7 and 155.5–159.7 pm, resp. |
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