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4-bromo-3,3-dimethyl-1-butene: a new probe for radical intermediates in reactions in strongly basic media
Authors:Martin Newcomb  William G Williams  Elizabeth L Crumpacker
Institution:Department of Chemistry, Texas A&M University, College Station, Texas 77843 USA
Abstract:The preparation, isolation and purification of the title bromide (1) are described, and the application of 1 as a mechanistic probe is demonstrated in the metal—halogen interchange reaction with tert-butyllithium.
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