Bridged ring a steroids: total synthesis of (±)-14β-hydroxy-1β,4β-methano-5β,8α,9β-androstane-7,17-dione |
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| Authors: | Stephen P Douglas Jeffery F Sawyer Peter Yates |
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| Institution: | Lash Miller Chemical Laboratories, University of Toronto Toronto, Ontario, Canada M5S 1A1 USA |
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| Abstract: | A modification of the Torgov steroid synthesis in which a vinyl methyl ether group in ring B stabilizes the critical cationic intermediate has been used to synthesize the title compound (15), whose structure has been confirmed by X-ray crystallographic analysis. |
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