Syntheses of dictyopterene B (hormosirene) and its enantiomer via asymmetric ScN′ reactions |
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Authors: | Dieter Dorsch Erika Kunz Günter Helmchen |
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Abstract: | Stereocontrolled syntheses of dictyopterene B (hormosirene) (1) and its enantiomer (ent-1) are reported. Key steps are highly stereoselective ScN′ reactions of esters of alcohols 2 and 5 derived from (+)-camphor. |
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