Efficient oxygen-atom transfer agent: photochemical hydroxylation of benzene derivatives by pyrimido[5,4-<span class="math"><math><mtext>g</mtext></math></span>]pteridine <span class="math"><math><mtext>n</mtext></math></span>-oxide期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Efficient oxygen-atom transfer agent: photochemical hydroxylation of benzene derivatives by pyrimido[5,4- $g$ ]pteridine $n$ -oxide

Authors:	Magoichi Sako Kaoru Shimada Kosaku Hirota Yoshifumi Maki

Affiliation:	Gifu Pharmaceutical University, 6-1, Mitahora-higashi 5 Chome, Gifu 502, Japan

Abstract:	Pyrimido[5,4- $g$ ]pteridine $N$ -oxide (1) oxidizes efficiently benzene, toluene, and anisole under UV irradiation to give the corresponding phenol derivatives 4, though the easiness of the reaction significantly depends upon the nature of the substituents on the benzene ring.

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