The bromination of 3-bromo-6,7-benzobicyclo[3.2.1]octa-2,6-diene |
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| Authors: | Mansur Harmandar Metin Balci |
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| Institution: | Faculty of Science, Department of Chemistry, Atatürk University, Erzurum/Turkey |
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| Abstract: | The bromination of 3-bromo-6, 7-benzobicyclo 3.2.1] octa-2, 6-diene at ?50°C has been found to give only one product, the tribromide(7) produced via Wagner-Meerwein rearrangement with accompanying aryl migration. The bromination at 0°C produced nonrearranged tribromides beside the rearranged product. The structures of the products were determined by means of spectral data. The addition mechanism is discussed in terms of exo- and endo-attack. |
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