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Synthesis of bicyclogermacrene and lepidozene |
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| Authors: | John E McMurry Gregory K Bosch |
| Institution: | Department of Chemistry, Baker Laboratory Cornell University, Ithaca, NY 14853 U.S.A. |
| Abstract: | Bicyclogermacrene (1) and lepidozene (2) have been synthesized by short routes starting from geranylacetone. Titanium-induced cyclizations of cis- and trans-2,2- dimethyl-3-(3-methyl-7-oxo-3E-octenyl)cyclopropane-carbaldehyde were used as the key steps. |
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