Reactions of diethylmagnesium - ethyllithium solutions with pyridine |
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Authors: | Herman G. Richey Julius Farkas |
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Affiliation: | Department of Chemistry, The Pennsylvania State University University Park, Pennsylvania 16802 U.S.A. |
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Abstract: | In contrast to the reactions of pyridine with diethylmagnesium or ethyllithium alone, which lead only to 1,2-addition, reactions with diethylmagnesium-ethyllithium solutions lead to significant amounts of 1,4-addition; magnesium ate species are proposed to be responsible. |
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