Syntheses of protected vinylic amino acids by intermolecular Lewis acid catalyzed ene reactions |
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Authors: | K Agouridas JM Girodeau R Pineau |
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Institution: | Centre de Recherche Delalande, Département de Chimie Organique, 10, rue des Carrières, 92500 Rueil-Malmaison France |
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Abstract: | Intermolecular ene reaction between ethylglyoxylate and allylic amino acid derivatives gave highly functionalized unsaturated pimelic acids in one step. This synthetic approach appears as a new efficient method for the synthesis of vinylic amino acids. |
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