A route to prostaglandin precursors from 1-(phenylthio)-2-octenyllithium.期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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A route to prostaglandin precursors from 1-(phenylthio)-2-octenyllithium.

Authors:	Malcolm R Binns Richard K Haynes Dale E Lambert Paul A Schober

Institution:	Department of Organic Chemistry, University of Sydney, Sydney NSW 2006, Australia

Abstract:	The enolates generated by the conjugate addition of 1-(phenylthio)-2-octenyllithium to 4- $tert$ -butoxycyclopent-2-en-1-one and <-crotonolactone react with methyl 7-halohept-5-ynoates in the presence of Ph₃SnCl to deliver products which may be converted into prostaglandin precursors.

Keywords:
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