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The meta photocycloaddition of anisole and benzonitrile to 1,3-dioxol-2-one
Authors:E.M. Osselton  C.P. Eyken  A.W.H. Jans  J. Cornelisse
Affiliation:Gorlaeus Laboratories, University of Leiden P.O. Box 9502, 2300 RA Leiden, The Netherlands
Abstract:The meta photocycloadditions of benzonitrile and anisole to 1,3-dioxol-2-one both yield two major products. In both cases the adducts are those which would be expected if some form of polar species were to develop along the reaction pathway. The absence of exo adducts in the case of benzonitrile and 1,3-dioxol-2-one is discussed.
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