Regioselectivity changes in hexane hydroxylation by iodozobenzene catalyzed by tetraarylporphyrinatoiron complexes |
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| Authors: | Alexander Khenkin Oskar Koifman Alexander Semeikin Alexander Shilov Albert Shteinman |
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| Institution: | 1. Institute of Chemical Technology, Ivanovo, U.S.S.R. |
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| Abstract: | Regioselectivity of hexane hydroxylation by iodozobenzene was correlated with electronic and steric constants of substituted porphyrins and revealed the increase of the relative rate of an attack at terminal methyl- and methylene-groups of hexene in sterically hindered and electron-deficient porphyrinatoiron complexes. |
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