Generation and thermal bond relocation of a sterically congested cyclononatetraenyl anion |
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Authors: | A.G. Anastassiou H.S. Kasmai M. Hasan |
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Affiliation: | 1. Departments of Chemistry Syracuse University Syracuse, New York 13210 U.S.A.;2. The University of Petroleum and Minerals Dhahran, Saudi Arabia |
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Abstract: | The sterically strained anion 4 was found to be thermally labile to subzero workup, readily undergoing temperature-dependent electrocyclization to a variety of tetracyclic frames. |
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