Regiospecific opening of oxetanes with trimethylsilyl cyanide - zinc iodide. a general approach to γ-amino alcohols. |
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| Authors: | Paul G Gassman Leonard M Haberman |
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| Institution: | Department of Chemistry, University of Minnesota, Minneapolis Minnesota 55455 U.S.A. |
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| Abstract: | Trimethylsilyl ethers of γ-hydroxy isonitriles were formed regiospecifically in the opening of oxetanes with trimethylsilyl cyanide - zinc iodide. Deprotection and hydrolysis of the initially formed ring cleavage products gave γ-amino alcohols. |
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