Iridoids : on the synthesis and structure of specionin |
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Authors: | E. Van der Eycken P. Callant M. Vandewalle |
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Affiliation: | State University of Ghent, Department of Organic Chemistry Laboratory for Organic Synthesis, Krijgslaan, 281 (S.4), B-9000 Gent Belgium |
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Abstract: | Recently, structure has been assigned to the iridoid specionin. In the present letter the total synthesis of is described. Comparison of spectral data reveals that the final product is not identical with natural specionin. Therefore the original structural assignment of specionin must be revised. |
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