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Iridoids : on the synthesis and structure of specionin
Authors:E. Van der Eycken  P. Callant  M. Vandewalle
Affiliation:State University of Ghent, Department of Organic Chemistry Laboratory for Organic Synthesis, Krijgslaan, 281 (S.4), B-9000 Gent Belgium
Abstract:Recently, structure 8b has been assigned to the iridoid specionin. In the present letter the total synthesis of 8b is described. Comparison of spectral data reveals that the final product is not identical with natural specionin. Therefore the original structural assignment of specionin must be revised.
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