The synthesis of structural analogues of the podophyllum lignans: selective wittig reactions on 1-aryl-2-methyl-tetrahydronaphthoic acid anhydride |
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| Authors: | John Mann Lilan TF Wong Andrew R Beard |
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| Institution: | Chemistry Department, University of Reading, Whiteknights, P.O.Box 224, Reading, Berkshire, RG6 2AD, England. |
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| Abstract: | The title anhydride reacts with stabilised phosphorus ylids exclusively at the carbonyl remote from the 1-aryl substituent. These products have been converted into a variety of compounds related in structure to deoxyisopicrophyllotoxin. |
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