Frontier orbital control in hydrazino bridged [14]annulenes |
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| Authors: | Wilhelm Flitsch Karin Rutkowski |
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| Affiliation: | Organisch-Chemisches Institut der Westfälischen Wilhelms-Universität Orléans-Ring 23. D-4400 Munster Germany |
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| Abstract: | [10b.10c]Diazapyraceheptylenes 1b and 1c were obtained from olefinic precursors 6. Treatment of 7 under the same conditions does not allow a synthesis of the parent compound 1a which may be explained by frontier orbital considerations. |
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