Facile generation of dialkylaminyl radicals from N-hydroxypyridine-2-thione carbamates. Application in kinetic studies of small ring cycloalkylaminyl radical ring openings |
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| Authors: | Martin Newcomb Jere Kaplan Donald J. Marquardt |
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| Affiliation: | Department of Chemistry Texas A&M University College Station Texas 77843 USA |
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| Abstract: | The preparation of N-hydroxypyridine-2-thione carbamates and the formation of dialkylaminyl radicals from these species are described and the application of this methodology in kinetic studies of aminyl radical rearrangements is demonstrated. |
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