Diastereoselectivity of the mercuration of acyclic allylic alcohols |
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Authors: | Bernd Giese Dieter Bartmann |
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Affiliation: | Institut für Organische Chemie und Biochemie Technische Hochschule Darmstadt Petersenstraβe 22, D-6100 Darmstadt, Germany |
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Abstract: | The diastereoselectivity of the mercuration of acyclic alkenes can be reversed by changing the substituent in the allylic position; with alcohols the erythro isomers and with esters or hemiacetals the threo isomers and are formed predominantly (Table I). |
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