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Towards tetrasilabicyclo[1.1.0]butane: reductive coupling of 1-t-butyl-2,2-dimesityl-1,1,2-trichlorodisilane
Authors:Scott Collins  James A Duncan  Yoshio Kabe  Shu Murakami  Satoru Masamune
Institution:Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, U.S.A.
Abstract:Reductive coupling of 1-t-butyl-2,2-dimesityl-1,1,2-trichlorodisilane employing Li-naphthalenide furnishes, on oxygenation or hydrolysis of the reaction mixture, products (8-11) that may arise from insertion of oxygen into or the addition of water across the Si-Si bonds of 1,3-di-t-butyl-2,2,4,4-tetramesityltetrasilabicyclo-1.1.0]butane (3).
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