Towards tetrasilabicyclo[1.1.0]butane: reductive coupling of 1-t-butyl-2,2-dimesityl-1,1,2-trichlorodisilane |
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Authors: | Scott Collins James A Duncan Yoshio Kabe Shu Murakami Satoru Masamune |
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Institution: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, U.S.A. |
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Abstract: | Reductive coupling of 1--butyl-2,2-dimesityl-1,1,2-trichlorodisilane employing Li-naphthalenide furnishes, on oxygenation or hydrolysis of the reaction mixture, products (-) that may arise from insertion of oxygen into or the addition of water across the Si-Si bonds of 1,3-di--butyl-2,2,4,4-tetramesityltetrasilabicyclo-1.1.0]butane (). |
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